Anandaram Sreekanth

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In the asymmetric unit of the title compound, C16H17N3O2S, there are two independent mol-ecules (A and B), which show an E conformation with respect to the C=N bond. An intra-molecular O-H⋯N hydrogen bond with an S(6) motif stabilizes the mol-ecular structure. The terminal phenyl and benzene rings are almost orthogonal to each other, the dihedral angle(More)
Cyclopropane and its derivatives (ER 2) 3 (E = C, Si, Ge, Sn), bicyclobu-tanes, and other strained hydrocarbons have remarkably low oxidation potentials when compared to their unstrained linear counterparts. [1–3] Can this property be translated to transition-metal complexes, such that small rings incorporating the transition metal lead to more facile(More)
In memoriam Professor Hanns Fischer This review discusses the application of pulse EPR to the characterization of disordered systems, with an emphasis on samples containing transition metals. Electron nuclear double-resonance (ENDOR), electron-spin-echo envelope-modulation (ESEEM), and double electron–electron resonance (DEER) methodologies are outlined.(More)
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