Amrita Mondal

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Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging N3- and an O-H...O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via N3- ligands and antiferromagnetic interactions through the H-bonded moiety. The overall magnetic behavior of the system(More)
The green colored complexes of the type Re(V)O(L(SB))Cl(2), 1, have been synthesised by reacting NBu(4)[ReOCl(4)] with HL(SB) in dry ethanol. Here, L(SB)(-) are the deprotonated forms of N-(2-hydroxybenzyl)-2-picolylamine (HL(SB)(1)); N-(2-hydroxybenzyl)-N',N'-dimethylethylenediamine (HL(SB)(2)) and N-(2-hydroxybenzyl)-N',N'-diethylethylenediamine(More)
Complexes of the general formula [Ni2L2(l1,1-N3)2(N3)2] have been synthesised in good yields by reacting Ni(NO3)2 Æ 6H2O wit L in the presence of excess of sodium azide in methanol at room temperature. Here L is N,N-bis(2-pyridylmethyl)amine (L) an N-(2-pyridylmethyl)-N 0,N 0-diethylethylenediamine (L). The X-ray structures of both compounds reveal that the(More)
Dinuclear (V(IV)V(V)) oxophenoxovanadates of general formula [V2O3L] have been synthesized in excellent yields by reacting bis(acetylacetonato)oxovanadium(IV) with H3L in a 2:1 ratio in acetone under an N2 atmosphere. Here L3- is the deprotonated form of 2,6-bis[{{(2-hydroxybenzyl)(N',N'-(dimethylamino)ethyl)}amino}methyl]-4-methylphenol (H3L1),(More)
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