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Being a major conception of chemistry, Lewis acids have found countless applications throughout chemical enterprise. Although many chemical elements can serve as the central atom of Lewis acids,… (More)
The synthesis of the novel title compounds is presented by using an important excess of base.
The Cu(I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily… (More)
N-Heterocyclic nitrenium cations are isostructural and isoelectronic analogues of the ubiquitous N-heterocyclic carbene. We present the first examples of coordination of nitrenium ions to the Ir(I)… (More)