Alexandre Nasr

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A highly efficient NIS-promoted iodocarbocyclization reaction of various functionalized 1,5-enynes is described via a 5-endo diastereoselective process. The cyclizations are conducted in the presence of 1.2 equiv of N-iodosuccinimide in dichloromethane at room temperature. The reaction conditions are compatible with several functional groups and lead to(More)
Coinage metal complexes of the N-heterocyclic carbene-phosphinidene adduct IPr⋅PPh (IPr=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) were prepared by its reaction with CuCl, AgCl, and [(Me2 S)AuCl], which afforded the monometallic complexes [(IPr⋅PPh)MCl] (M=Cu, Ag, Au). The reaction with two equivalents of the metal halides gave bimetallic(More)
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