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The gold(I) complexes AuCl(PR3)(PR3= PPh3, PMePh2, and PMe2Ph) react with Ti(η-C7H8)2 to form a variety of cationic gold cluster complexes; single-crystal X-ray analysis of one of these,Continue Reading
  • Laura E. Riley, Antony P. Y. Chan, +5 authors Igor B Sivaev
  • Medicine, Chemistry
  • Dalton transactions
  • 2016 (First Publication: 5 January 2016)
  • Doubly-deprotonated 1,1'-bis(o-carborane) reacts with [RuCl2(p-cymene)]2 to afford [Ru(κ3-2,2',3'-{1-(1'-1',2'-closo-C2B10H10)-1,2-closo-C2B10H10})(p-cymene)] (1) in which 1,1'-bis(o-carborane) actsContinue Reading
    The syntheses and characterisations of 1,2-Ph2-3-(η-C5Me5)-3,1,2-pseudocloso-IrC2B9H91, 1,2-Ph2-3-(η-C6H6)-3,1,2-pseudocloso-RuC2B9H92, 1,2-Ph2-3-(cym)-3,1,2-pseudocloso-RuC2B9H9(cym =p-cymene)3 andContinue Reading
    The isolation of six isomeric, low-symmetry, dicobaltacarboranes with bicapped hexagonal antiprismatic cage structures, always in low yield, is described from reactions in which 13-vertexContinue Reading