Alain Vallat

We don’t have enough information about this author to calculate their statistics. If you think this is an error let us know.
Learn More
Addition of formate on the dicationic cluster [Pd(3)(dppm)(3)(mu(3)-CO)](2+) (dppm=bis(diphenylphosphinomethane) affords quantitatively the hydride cluster [Pd(3)(dppm)(3)(mu(3)-CO)(mu(3)-H)](+). This new palladium-hydride cluster has been characterised by (1)H NMR, (31)P NMR and UV/Vis spectroscopy and MALDI-TOF mass spectrometry. The unambiguous(More)
The qualitative description of the major microstructure characteristics of microcrystalline silicon is achieved through a threedimensional discrete dynamical growth model. The model is based on three fundamental processes that determine surface morphology: (1) random deposition of particles, (2) local relaxation and (3) desorption. In this model, the(More)
The reduction mechanism of the title cluster has been investigated by means of cyclic voltammetry (CV), rotating disk electrode (RDE) voltammetry, and coulometry. The 2-electron reduction proceeds via two routes simultaneously. The first one involves two 1-electron reduction steps, followed by an iodide elimination to form the neutral Pd(3)(dppm)(3)(CO)(0)(More)
  • 1