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A variety of substrates containing hydroxy groups have been protected as their corresponding trimethylsilyl ethers using 1,1,1,3,3,3-hexamethyldisilazane in the presence of indium tribromide. The… (More)
Alcohols undergo smooth oxidation with iodoxybenzoic acid (IBX) or with Dess–Martin-Periodinane (DMP) in hydrophilic [bmim]BF4 and hydrophobic [bmim]PF6 ionic liquids at room temperature under mild… (More)
Amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of samarium(III) triflate at ambient temperature to produce the corresponding β-amino… (More)
Indoles, oxindoles and aromatic amino compounds undergo smooth thiocyanation with ammonium thiocyanate in the presence of anhydrous FeCl 3 in dichloromethane under mild conditions to afford the… (More)