Adrian G Amador

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Control of stereochemistry in photocycloaddition reactions remains a substantial challenge; almost all successful catalytic examples to date have involved [2 + 2] photocycloadditions of enones. We report a method for the asymmetric [3 + 2] photocycloaddition of aryl cyclopropyl ketones that enables the enantiocontrolled construction of densely substituted(More)
A light in dark places: The discovery of catalysts that can both promote photochemical reactions and control their stereochemistry has been regarded as a central challenge in photochemical synthesis for several decades. The discovery of chiral-at-metal complexes that seem particularly successful in this context is an exciting new development that may(More)
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