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With the advent of Internet of Things, the field of domain sensing is increasingly being servitized. In order to effectively support this servitization, there is a growing need for a powerful and easy-to-use infrastructure that enables seamless sharing of sensor data in real-time. In this paper, we present the design and evaluation of Data Quality-Aware… (More)
An important component of current research in big data is graph analytics on very large graphs. Of the many problems of interest in this domain, graph pattern matching is both challenging and practically important. The problem is, given a relatively small query graph, finding matching patterns in a large data graph. Algorithms to address this problem are… (More)
This supplement to the paper provides all figures and substantial code listings which would not fit into the paper due to page limitations. Roadmap: The supplement is organized in the same manner as the main paper i.e. the section names in the main paper corresponds to the same section in the supplement for the easy reference. Note: In many cases, text from… (More)
5-Endo-trig cyclizations are generally considered to be kinetically unfavourable, as described by Baldwin's rules. Consequently, observation of this mode of reaction under kinetic control is rare. This is usually ascribed to challenges in achieving appropriate approach trajectories for orbital overlap in the transition state. Here, we describe a highly… (More)
Homo- and heterochiral tetrameric gamma-peptide derivatives in which the backbone is constrained by a five-membered ring populate a bend-ribbon conformation in solution stabilized by intramolecular hydrogen bonds.