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Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle.
A derivation of chemical equilibrium equations for a spherical thin film of solution around a soluble solid nanoparticle is presented. The equations obtained generalize the Gibbs-Kelvin-Kohler and… Expand
Thermodynamic Characteristics of Micellization in the Droplet Model of Surfactant Spherical Molecular Aggregate
The dependence of the work of the molecular aggregate formation on the aggregation number and surfactant monomer concentration in solution that has the key role for the theory of micellization was… Expand
Kinetics of Aggregation in Micellar Solutions
Small parameters were introduced for describing the kinetics of aggregation of nonionic surfactants in solutions in an analytical form. The direct and reverse transition of molecular aggregates over… Expand
Grand potential in thermodynamics of solid bodies and surfaces.
- A. I. Rusanov, A. Shchekin, D. V. Tatyanenko
- Chemistry, Physics
- The Journal of chemical physics
- 8 October 2009
Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic… Expand
Thermodynamic and kinetic theory of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets on soluble particles.
- A. Shchekin, I. V. Shabaev, O. Hellmuth
- Chemistry, Medicine
- The Journal of chemical physics
- 1 February 2013
Thermodynamic and kinetic peculiarities of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets formed on soluble condensation nuclei from a solvent vapor have been… Expand
Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities
Abstract. In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by… Expand
New analytical TEMOM solutions for a class of collision kernels in the theory of Brownian coagulation
New analytical solutions in the theory of the Brownian coagulation with a wide class of collision kernels have been found with using the Taylor-series expansion method of moments (TEMOM). It has been… Expand
Validity of Tolman's equation: How large should a droplet be?
Surface tension and the length δ (distance between the Gibbs surface of tension Rs and the equimolar surface Re) of simple liquid droplet (Lennard-Jones and Yukawa) are computed over a wide range of… Expand
Excess equimolar radius of liquid drops.
- M. Horsch, H. Hasse, +5 authors G. Jackson
- Materials Science, Physics
- Physical review. E, Statistical, nonlinear, and…
- 11 May 2011
The curvature dependence of the surface tension is related to the excess equimolar radius of liquid drops, i.e., the deviation of the equimolar radius from the radius defined by the macroscopic… Expand
Thermodynamic and Kinetic Foundations of the Micellization Theory: 4. Kinetics of Establishment of Equilibrium in a Micellar Solution
A system of the kinetic equations of the material balance for the concentrations of surfactant monomers and micelles in a micellar nonionic surfactant solution was formulated. The equilibrium state… Expand