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Publications Influence

Generalization of the Gibbs-Kelvin-Kohler and Ostwald-Freundlich equations for a liquid film on a soluble nanoparticle.

- A. Shchekin, A. I. Rusanov
- Materials Science, Medicine
- The Journal of chemical physics
- 21 October 2008

A derivation of chemical equilibrium equations for a spherical thin film of solution around a soluble solid nanoparticle is presented. The equations obtained generalize the Gibbs-Kelvin-Kohler and… Expand

48 2- PDF

Thermodynamic Characteristics of Micellization in the Droplet Model of Surfactant Spherical Molecular Aggregate

- A. I. Rusanov, F. M. Kuni, A. Grinin, A. Shchekin
- Chemistry
- 1 September 2002

The dependence of the work of the molecular aggregate formation on the aggregation number and surfactant monomer concentration in solution that has the key role for the theory of micellization was… Expand

25 2- PDF

Kinetics of Aggregation in Micellar Solutions

- F. M. Kuni, A. I. Rusanov, A. Shchekin, A. Grinin
- Chemistry
- 2005

Small parameters were introduced for describing the kinetics of aggregation of nonionic surfactants in solutions in an analytical form. The direct and reverse transition of molecular aggregates over… Expand

22 1- PDF

Grand potential in thermodynamics of solid bodies and surfaces.

- A. I. Rusanov, A. Shchekin, D. V. Tatyanenko
- Chemistry, Physics
- The Journal of chemical physics
- 8 October 2009

Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic… Expand

18 1- PDF

Thermodynamic and kinetic theory of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets on soluble particles.

- A. Shchekin, I. V. Shabaev, O. Hellmuth
- Chemistry, Medicine
- The Journal of chemical physics
- 1 February 2013

Thermodynamic and kinetic peculiarities of nucleation, deliquescence and efflorescence transitions in the ensemble of droplets formed on soluble condensation nuclei from a solvent vapor have been… Expand

11 1

Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities

- O. Hellmuth, A. Shchekin
- Chemistry
- 8 September 2014

Abstract. In order to study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour, we have employed a thermodynamic approach proposed by… Expand

7 1- PDF

New analytical TEMOM solutions for a class of collision kernels in the theory of Brownian coagulation

- Q. He, A. Shchekin, M. Xie
- Mathematics
- 15 June 2015

New analytical solutions in the theory of the Brownian coagulation with a wide class of collision kernels have been found with using the Taylor-series expansion method of moments (TEMOM). It has been… Expand

12 1

Validity of Tolman's equation: How large should a droplet be?

- K. Koga, X. Zeng, A. Shchekin
- Chemistry
- 30 September 1998

Surface tension and the length δ (distance between the Gibbs surface of tension Rs and the equimolar surface Re) of simple liquid droplet (Lennard-Jones and Yukawa) are computed over a wide range of… Expand

96- PDF

Excess equimolar radius of liquid drops.

- M. Horsch, H. Hasse, +5 authors G. Jackson
- Materials Science, Physics
- Physical review. E, Statistical, nonlinear, and…
- 11 May 2011

The curvature dependence of the surface tension is related to the excess equimolar radius of liquid drops, i.e., the deviation of the equimolar radius from the radius defined by the macroscopic… Expand

34- PDF

Thermodynamic and Kinetic Foundations of the Micellization Theory: 4. Kinetics of Establishment of Equilibrium in a Micellar Solution

- F. M. Kuni, A. Grinin, A. Shchekin, A. I. Rusanov
- Chemistry
- 1 March 2001

A system of the kinetic equations of the material balance for the concentrations of surfactant monomers and micelles in a micellar nonionic surfactant solution was formulated. The equilibrium state… Expand

17- PDF

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