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Determination of enantiomeric excess by chiral liquid chromatography without enantiomerically pure starting standards.
- F. Sánchez, A. Navas Díaz, E. Sánchez Torreño, A. Aguilar, I. Medina Lama, M. Algarra
- Chemistry, Medicine
- Biomedical chromatography : BMC
- 1 October 2012
A facile approach for the enantiomeric excess determination of enantiomeric mixtures without the necessity of pure enantiomer standards is presented. Promethazine and trimeprazine commercial… Expand
Enhancer effect of fluorescein on the luminol-H2O2-horseradish peroxidase chemiluminescence: energy transfer process.
- A. Navas Díaz, J. G. González García, J. Lovillo
- Chemistry, Medicine
- Journal of bioluminescence and chemiluminescence
- 1 July 1997
The chemiluminescence of the luminol-H2O2-horseradish peroxidase system is increased by fluorescein. Fluorescein produces an enhancement of the luminol chemiluminescence similar to that of… Expand
Determination of asulam by fast stopped-flow chemiluminescence inhibition of luminol/peroxidase.
- F. García Sánchez, A. Navas Díaz, C. Delgado Téllez, M. Algarra
- Chemistry, Medicine
- Talanta
- 19 October 2008
An efficient, sensitive and fast stopped-flow method has been developed to determine asulam in water, based on its inhibition effect on the horseradish peroxidase-luminol-hydrogen peroxide… Expand
Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution.
- F. García Sánchez, M. Cedazo, J. Lovillo, A. Navas Díaz
- Chemistry, Medicine
- Talanta
- 1 August 1996
The potential of variable angle synchronous spectroscopy (VASS) for fluorescent mixtures resolution was assessed and compared with the rank annihilation method (RAM). For this purpose, a set of… Expand
Enhancement and inhibition of luminol chemiluminescence by phenolic acids.
- A. Navas Díaz, F. García Sánchez, J. G. González García
- Medicine
- Journal of bioluminescence and chemiluminescence
- 1995
We explored the behaviour of a series of phenolic acids used as enhancers or inhibitors of luminol chemiluminescence by three different methods to determine if behaviour was associated with phenolic… Expand
Photophysical behaviour of 2-(dimethylamino)-fluorene in organised assemblies
- F. García Sánchez, M. Algarra, J. Lovillo, A. Aguilar, A. Navas Díaz
- Chemistry
- 1 April 2010
The effects of cyclodextrins and TX-100 micelles on the fluorescent properties of 2-(dimethylamino)-fluorene (DAF) were studied. The photophysical properties of DAF in the micelle aggregates and… Expand
Resolution of (+)-cinchonine and (-)-cinchonidine by phase-modulation fluorescence spectroscopy.
- F. García Sánchez, A. Navas Díaz, M. C. Torijas, E. Nava Baro, M. Algarra
- Chemistry, Medicine
- Analytica chimica acta
- 20 April 2009
The different fluorescence lifetime profiles of the optical isomers (+)-cinchonine (CN) and (-)-cinchonidine (CD) have been used to resolve their mixtures, on the basis of phase and modulation… Expand
HPLC enantioseparation of alkaloid malacitanine using fluorimetric/polarimetric detection.
- F. García Sánchez, A. Navas Díaz, A. Aguilar, I. Medina Lama, M. Algarra
- Chemistry, Medicine
- Journal of separation science
- 1 August 2012
This work reports two methods developed for the separation and determination of the enantiomers of the new alkaloid malacitanine (MLC) and the determination of the enantiomeric purity in mixtures.… Expand
Chemiluminescent lipase determination based on the enhanced luminol/H2O2/horseradish peroxidase/fluorescein diacetate energy transfer system
- A. Navas Díaz, F. G. Sánchez, M. C. Torijas, J. Lovillo
- Chemistry
- 8 November 1999
Abstract A methodology for the determination of lipase, based on the coupled processes of energy transfer and enhancement of the chemiluminescence of the luminol-H2O2-horseradish peroxidase (HRP)… Expand
Phenol derivatives as enhancers and inhibitors of luminol-H2O2-horseradish peroxidase chemiluminescence.
- A. Navas Díaz, F. García Sánchez, J. G. González García
- Medicine
- Journal of bioluminescence and chemiluminescence
- 1998
Systematic studies on phenol derivatives facilitates an explanation of the enhancement or inhibition of the luminol-H2O2-horseradish peroxidase system chemiluminescence. Factors that govern the… Expand