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Oxidation of n-Propylamine and n-Butylamine by Chloramine-B and Chloramine-T in Basic Medium: A Kinetic Study
The oxidation of aliphatic primary amines, n-propylamine (PA) and -butylamine (BA), by chloramine-B (CAB) and chloramine-T (CAT) in aqueous alkaline medium has been kinetically studied at 318 K. The
Kinetics of oxidation ofa-amino acids by sodium N-bromo benzenesulfonamide
Oxidations of glycine, valine, leucine, alanine and phenylalanine by the title reagent have been performed near their isoelectric pH, at 35 °C. The rate law is-d log[BAB]/dt=k′[Amino acid]x where x
Some complexes of zinc(II), cadmium(II), and mercury(II) with thiosemicarbazide
ZnL2(NO3)2, ZnL2(ClO4)2, CdL2Cl2, and HgL2Cl2 were obtained by mixing aq. solns. of thiosemicarbazide (L) and the corresponding salts in a 2:1 molar ratio. By elemental anal. and ir spectral studies,
Distribution of Isomorphous Salts between Aqueous and Solid Phases in Fractional Crystallization. Nickel Ammonium Sulfate-Magnesium Ammonium Sulfate-Water and Barium Nitrate-Lead Nitrate-Water Systems
The distribution of isomorphous salts between aq. and solid phases in fractional crystn. was detd. The results were examd. from the standpoint of theoretical equations developed by Doerner and