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- Publications
- Influence
A Kirkwood-Buff analysis of local properties of solutions.
- A. Ben-Naim, A. M. Navarro, J. Leal
- Chemistry, Medicine
- Physical chemistry chemical physics : PCCP
- 30 April 2008
For decades, the properties of liquid mixtures have been analyzed in terms of excess thermodynamic functions. These functions convey global or macroscopic information on the system. In this work, a… Expand
Preferential solvation in alkan-1-ol/alkylbenzoate binary mixtures by solvatochromic probes.
- A. M. Navarro, B. García, F. J. Hoyuelos, Indalecio A. Peñacoba, J. M. Leal
- Chemistry, Medicine
- The journal of physical chemistry. B
- 8 August 2011
The binary mixtures of methanol with (C(1)-C(4)) alkylbenzoates and of (C(1), C(3), C(5), C(7), C(9), C(11)) alkan-1-ols with methylbenzoate were used as solvents to look into the preferential… Expand
Measurements and Modeling of Thermophysical Behavior of (C1 − C4) Alkylbenzoate/ (C1 − C11) Alkan-1-ol Mixed Solvents
- B. García, S. Aparicio, A. M. Navarro, and Rafael Alcalde, J. M. Leal
- Chemistry
- 14 September 2004
The thermophysical properties of the (C1−C11) alkan-1-ol/(C1−C4) alkylbenzoate mixed solvents at atmospheric pressure and 298.15 K were studied over the whole composition range. The intermolecular… Expand
Microwave dielectric relaxation spectroscopy study of alkan-1-ol/alkylbenzoate binary solvents.
- A. M. Navarro, B. García, S. Ibeas, F. J. Hoyuelos, Indalecio A. Peñacoba, J. M. Leal
- Chemistry, Medicine
- The journal of physical chemistry. B
- 16 September 2013
The structure and dynamics of alkan-1-ol/alkylbenzoate binary mixtures have been studied by microwave dielectric relaxation spectroscopy in the 200 MHz to 20 GHz frequency range. The binary mixtures… Expand
Acid–base behaviour of organopalladium complexes [Pd(CNN)R]BF4
- M. S. Muñoz, B. García, +4 authors J. M. Leal
- Chemistry
- 8 December 2004
Protonation of the orthopalladated carbon of the cyclometallated complex [Pd(CNN)L]+, where L = P(OMe)3 and HCNN is the C-deprotonated form of the tricoordinated chelant donor ligand… Expand
Phosphine and thiophene cyclopalladated complexes: hydrolysis reactions in strong acidic media.
- B. García, F. J. Hoyuelos, +4 authors J. M. Leal
- Chemistry, Medicine
- Chemistry, an Asian journal
- 3 December 2010
The mechanisms for the hydrolysis of organopalladium complexes [Pd(CNN)R]BF(4) (R=P(OPh)(3), PPh(3), and SC(4)H(8)) were investigated at 25 °C by using UV/Vis absorbance measurements in 10 % v/v… Expand
Protonation Sites of Indoles and Benzoylindoles
- F. J. Hoyuelos, B. García, +4 authors J. M. Leal
- Chemistry
- 1 March 2005
Indomethacine (1) and acemethacine (2) contain the substituents -OCH3, -CH2COOH, -CH2COOCH2COOH, C-indole and O-benzoyl, which are susceptible to protonation in highly acidic media. To determine the… Expand
Unequal effect of ethanol-water on the stability of ct-DNA, poly[(dA-dT)]₂ and poly(rA)·poly(rU). Thermophysical properties.
- R. Ruiz, F. J. Hoyuelos, A. M. Navarro, J. M. Leal, B. García
- Chemistry, Medicine
- Physical chemistry chemical physics : PCCP
- 21 January 2015
Ethanol affects unequally the thermal stability of DNA and RNA. It stabilizes RNA, while destabilizing DNA. The variation of the relative viscosity (η/η0) of [poly(dA-dT)]2 with temperature unveils… Expand
Evaluation of proton activity in microemulsions by a kinetic probe.
- Indalecio A. Peñacoba, B. García, A. M. Navarro, F. J. Hoyuelos, J. M. Leal
- Chemistry, Medicine
- Journal of colloid and interface science
- 15 December 2010
The decomposition reaction of the purple dye murexide in acidic media is used as a probe indicator for protons in nonionic microemulsions. The reaction kinetics primarily rely on the proton… Expand