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Abstract The kinetics and thermodynamics of the isomerization of syn- and anti-[Fe(SCH3)(CO3)]2 were investigated over the temperature range 40–70°C in chloroform and other solvents. In chloroform… (More)
Ir and Rh complexes of the title ligand (II) such as (III) and (X) as well as their carbonyl and chlorocarbonyl derivatives (VI)-(VIII), (XII), and (XVb) are prepared according to the scheme starting… (More)
Separation des agregats Os-Au, Ru-Au, Re-Au et Pt-Au et des agregats d'Au de type [Au n (PPh 3 ) m ] x+
[Ir 2 S(SH)(H) 3 (PPh 3 ) 4 ]BF 4 •2CH 3 ) 2 CO cristallise dans le systeme triclinique, groupe d'espace P1 et sa structure est affinee jusqu'a R=0,056. [Ir 2 S(SH)(H) 3 (PPh 3 ) 4 ]•1.5C 6 H 6… (More)