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Palladium coordination compounds as anti-viral, anti-fungal, anti-microbial and anti-tumor agents
Abstract Pd(II) complexes of various donor atom ligands posses anti-tumor and anti-viral, -malarial, -fungal and -microbial activities. This review focuses on such properties of Pd(II) complexes andExpand
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Preparation, crystal structure and solution studies of [Mn2L2Cl4(H2O)2], where L=2-(2′-pyridyl)quinoxaline
Abstract The reaction of MnCl2·4H2O with the biheteroaromatic ligand (L), formed the dinuclear complex bis[aquachloro-2-(2′-pyridyl)quinoxaline]di-μ-chloro dimanganese {[Mn2L2Cl4(H2O)2]}, which wasExpand
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Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N′-bis[1–(2–pyridyl)ethylidene]ethane-1,2–diamine
Cu(NO3)2·3H2O reacts with 1 equiv. of the tetradentate Schiff base N,N′-bis[1–(2–pyridyl)ethylidene]ethane-1,2–diamine (LA) in refluxing acetone to yield the [CuLA(ONO2)(H2O)](NO3) complex in ca. 80%Expand
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Synthesis, characterization, in vitro antitumor activity, DNA-binding properties and electronic structure (DFT) of the new complex cis-(Cl,Cl)[RuIICl2(NO+)(terpy)]Cl.
The complex cis-(Cl,Cl)-[RuCl2(terpy)(NO)]Cl (1) has been synthesized by the reaction of [RuCl3(H2O)2(NO)] with terpyridine (terpy) and characterized by various spectroscopic, analytical techniquesExpand
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Solid-phase synthesis, characterization and DNA binding properties of the first chloro(polypyridyl)ruthenium conjugated peptide complex.
A general method for the synthesis of chloro(polypyridyl)ruthenium conjugated peptide complexes via a solid-phase strategy is described. The method is applied to synthesize two positional isomers ofExpand
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1:1 Metal complexes of 2-(2′-pyridyl)quinoxaline, a ligand unexpectedly formed by the reaction between 2-acetylpyridine and 1,2-phenylenediamine
The complexes [MLCl2] (M=Co, Ni, Cu, Zn), where L is the new ligand 2-(2′-pyridyl)quinoxaline derived unexpectedly from 2-acetylpyridine and 1,2-phenylenediamine, were isolated. The ligand and itsExpand
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Multinuclear 1D and 2D NMR investigations on the interaction between the pyrimidic nucleotides 5 '-CMP, 5 '-dCMP, and 5 '-UMP and diethyltin dichloride in aqueous medium
The interactions between diethyltin dichloride and 5'-CMP, 5'-dCMP, and 5'-UMP in aqueous solution were investigated by multinuclear 1D and 2D NMR techniques including 119Sn, 15N and 31P nuclei.Expand
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Synthesis, characterization and DNA binding properties of oligopyridine-ruthenium(II)-amino acid conjugates.
The DNA-binding properties of a number of ruthenium oligopyridine complexes with conjugated amino acids having the general formulae [Ru(terpy)(4-COY-4'-Mebpy)(X)](n)(+), X=NO (n=3), X=Cl (n=1) andExpand
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Sequence-selective metal ion binding to DNA oligomers.
Sequence-selective interactions between DNA oligonucleotides and Pt(II) and Pd(II) complexes have been studied by 1D and 2D NMR spectroscopy. Titration of DNA oligomers with diamagnetic metal ionExpand
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Synthesis and characterization of the diastereomers Lambda- and Delta-[Ru(bpy)2(m-bpy-L-Arg-Gly-L-Asn-L-Ala-L-His-L-Glu-L-Arg)]Cl2 1H NMR studies on their interactions with the deoxynucleotide duplex
The diastereomeric complexes Lambda- and Delta-[Ru(bpy)(2)(m-bpy-7p)]Cl(2), (bpy=2,2'-bipyridine, m-bpy-7p=4-methyl-4'-Arg-Gly-Asn-Ala-His-Glu-Arg-CONH(2)-2,2'-bipyridine) were synthesized andExpand
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