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POLYPYRROLE FILMS CONTAINING METAL COMPLEXES : SYNTHESES AND APPLICATIONS
Electroreduction of CO2 catalyzed by polymeric [Ru(bpy)(CO)2]n films in aqueous media: Parameters influencing the reaction selectivity
[Mn(bipyridyl)(CO)3Br]: an abundant metal carbonyl complex as efficient electrocatalyst for CO2 reduction.
Manganese at work: carbonyl bipyridyl complexes based on manganese, a non-noble abundant and inexpensive metal, have been proved to be excellent molecular catalysts for the selective electrochemical…
Electrocatalytic reduction of CO2 into formate with [(η5Me5C5)M(L)Cl]+ complexes (L = 2,2′-bipyridine ligands; M Rh(III) and Ir(III))
Towards new molecular photocatalysts for CO2 reduction: photo-induced electron transfer versus CO dissociation within [Os(NN)(CO)2Cl2] Complexes.
- J. Chauvin, F. Lafolet, S. Chardon-Noblat, A. Deronzier, Minna Jakonen, M. Haukka
- 4 April 2011
The efficient oxidation and reduction of both complexes under continuous irradiation in the presence of a sacrificial electron acceptor or donor is reported here and the nature of the resulting compounds were analysed.
Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox…
Two new terpyridine dimanganese oxo complexes have been synthesized and their X-ray structures determined and the electrochemical behavior of 3 in organic medium shows that this complex could be oxidized into its corresponding stable manganese(IV,IV) species while its reduced form manganae(III,III) is very unstable and leads by a disproportionation process to Mn(II) and Mn(IV) complexes.
Binuclear manganese compounds of potential biological significance. 1. Syntheses and structural, magnetic, and electrochemical properties of dimanganese(II) and -(II,III) complexes of a bridging…
Magnetic measurements revealed that the three compounds exhibit very similar magnetic exchange interactions, and tentative magneto-structural correlations were established which show that for the dimanganese(II) complexes -J decreases when the Mn-O(phenoxo) distance increases as expected from orbital overlap considerations.
Electrochemical immobilization of glucose oxidase in poly(amphiphilic pyrrole) films and its application to the preparation of an amperometric glucose sensor
Synthesis and characterization of a new kind of Mn2III,IV µ-oxo complex: [Mn2O2(terpy)2(H2O)2](NO3)3·6 H2O, terpy=2,2′:6′,2″-terpyridine
A new kind of mixed-valence binuclear µ-oxo complex of manganese having two aqua ligands has been synthesized and structurally characterized.