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1,10-Phenanthroline: A versatile building block for the construction of ligands for various purposes
Abstract This review will cover the developments in the chemistry of phenanthroline-based ligands in the last 10–15 years. 1,10-Phenanthroline (phen) is a classic ligand in coordination chemistry,Expand
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Mortality among discharged psychiatric patients in Florence, Italy.
OBJECTIVE Psychiatric disorders involve an increased risk of mortality. In Italy psychiatric services are community based, and hospitalization is mostly reserved for patients with acute illness. ThisExpand
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ZnII Complex with a Phenanthroline-Containing Macrocycle as Receptor for Amino Acids and Dipeptides − Hydrolysis of an Activated Peptide Bond
The interaction between several L-amino acids and dipeptides and the ZnII complex with ligand L, a macrocycle containing a triamine chain linking the 2,9 positions of a phenanthroline moiety, hasExpand
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Therapeutic Effects of the Superoxide Dismutase Mimetic Compound MnIIMe2DO2A on Experimental Articular Pain in Rats
Superoxide anion (O2  •−) is overproduced in joint inflammation, rheumatoid arthritis, and osteoarthritis. Increased O2  •− production leads to tissue damage, articular degeneration, and pain. InExpand
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Carboxy and Phosphate Esters Cleavage with Mono- and Dinuclear Zinc(II) Macrocyclic Complexes in Aqueous Solution. Crystal Structure of [Zn(2)L1(&mgr;-PP)(2)(MeOH)(2)](ClO(4))(2) (L1 =
The ligand [30]aneN(6)O(4) (L1) binds two Zn(II) in aqueous solution. The stability constants of the L1 complexes have been determined at 308.1 K by means of potentiometric measurements. DinuclearExpand
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Tailoring cyclic polyamines for inorganic/organic phosphate binding.
In this tutorial review, we will discuss the most significant achievements in the structure-based design of cyclic receptors containing mainly aliphatic amine groups as metal-free hosts forExpand
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Zn(II) coordination to polyamine macrocycles containing dipyridine units. New insights into the activity of dinuclear Zn(II) complexes in phosphate ester hydrolysis.
Zn(II) binding by the dipyridine-containing macrocycles L1-L3 has been analyzed by means of potentiometric measurements in aqueous solutions. These ligands contain one (L1, L2) or two (L3)Expand
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Exploring the binding ability of polyammonium hosts for anionic substrates: selective size-dependent recognition of different phosphate anions by bis-macrocyclic receptors.
Binding of mono-, di-, and triphosphate, adenosine diphosphate (ADP), and adenosine triphosphatase (ATP) with receptors L1-L3, composed of two [9]aneN(3) units separated by aExpand
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Effect of the SOD mimetic MnL4 on in vitro and in vivo oxaliplatin toxicity: Possible aid in chemotherapy induced neuropathy.
BACKGROUND One of the most discomfortable dose-limiting adverse reactions of effective drugs for the treatment of solid tumors is a peripheral neuropathy which is the main reason for dose reductionExpand
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