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  • 沈金瑞, 周哲, 周远, 卢翠芬, 杨桂春, 陈祖兴
  • Chemistry
  • 2017 (First Publication: 30 October 2017)
  • 以双夹板形的笼型倍半硅氧烷(DDSQ)和叔丁基氧羰基(Boc)保护的C 2 -对称双脯氨酰胺为底物,通过硅氢加成反应和脱Boc反应,制得主链含DDSQ的C 2 -对称双脯氨酰胺手性聚合物催化剂;对其化学结构、分子量及热失重性能进行了表征. 将制备的聚合物催化剂应用于催化不对称Aldol反应,探讨了其催化性能.Continue Reading